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In the title compound, [Ru(C4H3N2S)2(C18H15P)2]·CHCl3, the Ru atom has a distorted octahedral environment formed by two S and two N atoms from the pyrimidine-2-thiol­ate ligands and two P atoms from the tri­phenyl­phosphine ligands. Intramolecular π–π interactions between the pyrimidine and phenyl rings of tri­phenyl­phosphine are observed.
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