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The title compound, C21H21N2O+·Br·0.5H2O, crystallizes in a monoclinic unit cell with two cations, two anions and one water mol­ecule in the asymmetric unit. The conformations of the two independent cations are different. The crystal packing is stabilized by O—H...Br and C—H...Br interactions and weak intermolecular C—H...O hydrogen bonds.

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The title compound, C14H18N2O3, is a potential anti-amnesic agent. The pyrrolidine ring is disordered and both major and minor components adopt an envelope conformation. In the solid state, symmetry-related mol­ecules are linked by inter­molecular N—H...O hydrogen bonds, forming chains with a C(10) graph-set motif. Inter­molecular C—H...O inter­actions are also observed.
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