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In the title complex, C8H12N2·2C6H5NO3, one 2,3,5,6-tetra­methyl­pyrazine and two p-nitro­phenol mol­ecules form a centrosymmetric unit. Intermolecular O—H...N and weak C—H...O hydrogen bonds are observed in the structure, leading to the formation of a two-dimensional network.

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In the title complex, 2C9H10O4·C8H12N2, there is an inversion centre at the centre of the 2,3,5,6-tetra­methyl­pyrazine mol­ecule, which is linked to two endo-norbornene-cis-5,6-di­carboxyl­ic acid mol­ecules via O—H...N hydrogen bonds. In the crystal structure, O—H...O and O—H...N hydrogen bonds propagate a one-dimensional zigzag chain, which is extended into layers when combined with longer C—H...O hydrogen bonds.

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The title mol­ecule, C18H18O8, has C2 molecular symmetry. In the crystal structure, each mol­ecule is connected to four neighbours via intermolecular O—H...O hydrogen bonds to form a two-dimensional network parallel to (100).

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In the title centrosymmetric compound, [Cd(C6H4FN2O4)2(C7H6N2)2(H2O)2], the cadmium(II) cation is coordinated by one O atom from each 5-fluoro-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidine-1-acetate anion, one N atom from each benzimidazole ligand and two water mol­ecules. The geometry around the cadmium(II) cation, which is located on a center of inversion, is distorted octa­hedral. Mol­ecules, which function as supramolecular blocks, are linked by inter­molecular N—H...O and O—H...O hydrogen bonds into a three-dimensional supramolecular network, which is reinforced by π–π inter­actions.
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