metal-organic compounds
Open access
The asymmetric unit of the title compound, [Ni(C32H36N4)], contains two independent molecules exhibiting an overall ruffled conformation of the porphyrin macrocycle and differing mainly in the positions of the methyl groups. The average Ni-N bond lengths are 1.912 (2) and 1.910 (2) Å in the two molecules. The molecules form a closely spaced lattice structure in which neighbouring porphyrins are oriented in a nearly perpendicular fashion to each other. The compound was prepared via nucleophilic substitution of (5,15-diisobutylporphyrinato)nickel(II) with n-butyllithium.