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In the title compound, C26H27N3O2, the morpholine ring adopts a chair conformation. The benzene and phenyl rings are inclined to the benzimidazole mean plane by 7.28 (6) and 61.45 (4)°, respectively. In the crystal, pairs of weak C—H
O hydrogen bonds link the molecules into inversion dimers. These dimers are further connected via weak C—HN hydrogen bonds. A weak C—Hπ interaction is also observed.
O hydrogen bonds link the molecules into inversion dimers. These dimers are further connected via weak C—HN hydrogen bonds. A weak C—Hπ interaction is also observed.organic compoundsOpen access
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In the title compound, C26H26ClN3O2·C3H7OH, the benzimidazole ring system is essentially planar [maximum deviation = −0.018 (2) Å] and its mean plane is oriented with respect to the two benzene rings at dihedral angles of 4.51 (6) and 56.16 (6)°, and the dihedral angle between the two benzene rings is 59.11 (7)°. The morpholine ring displays a chair conformation. The propan-2-ol solvent molecule links with the benzimidazole ring via an O—HN hydrogen bond. In the crystal, weak intermolecular C—HO hydrogen bonds link the molecules into inversion dimers with an R22(28) motif. π–π stacking occurs between the parallel chlorobenzene rings [centroid–centroid distance = 3.792 (1) Å]. Weak C—Hπ interactions and short ClCl [3.2037 (10) Å] contacts are also observed.
N hydrogen bond. In the crystal, weak intermolecular C—HO hydrogen bonds link the molecules into inversion dimers with an R22(28) motif. π–π stacking occurs between the parallel chlorobenzene rings [centroid–centroid distance = 3.792 (1) Å]. Weak C—Hπ interactions and short ClCl [3.2037 (10) Å] contacts are also observed.
