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In the title compound, [Fe4(C6H12N2S4)(C18H15P)2(CO)10], the unit cell contains one mol­ecule, which exhibits a crystallographically imposed center of symmetry. The independent Fe2S2 fragment [Fe—Fe = 2.527 (1) Å] is in a butterfly conformation, and each Fe atom displays a pseudo-square-pyramidal coordination geometry. The phosphane group occupies an apical position [Fe—P = 2.2670 (14) Å]. In the crystal, weak inter­molecular C—H...O hydrogen bonds link the mol­ecules into chains along [110].
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