metal-organic compounds
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In the crystal structure of the title compound, (C10H16N)2[Hg2Br6], the condensed anion consists of two edge-sharing HgBr4 tetrahedra and is situated on a centre of symmetry. The anions are linked to the cations through weak C—HBr interactions.
metal-organic compounds
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In the title compound, (C10H24N)[FeCl4], no classical hydrogen bonds are observed. The butyltriethylammonium cations interact with the tetrahedral [FeCl4]− anion through weak C—HCl interactions, forming a three-dimensional network.
metal-organic compounds
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In the title molecular salt, (C10H24N)2[Hg2Br6], the complete anion is generated by crystallographic inversion symmetry, forming a pair of edge-sharing HgBr4 tetrahedra. In the crystal, the cations and anions are linked by weak C—HBr interactions.
metal-organic compounds
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In the title molecular salt, (C11H16NO)[FeCl4], an intramolecular N—HO hydrogen bond in the cation generates an S(6) loop and the conformation of the C(=O)—C—C—N chain is gauche [torsion angle = 57.0 (6)°]. The anion is a near-regular tetrahedron [range of Cl—Fe—Cl angles = 107.93 (8)–112.13 (10)°]. There are no directional inter-ionic bonds in the crystal.
metal-organic compounds
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In the title molecular salt, (C13H22N)[FeCl4], three of the chloride ions of the tetrahedral FeIII-containing anion are disordered over two orientations in a 0.656 (11):0.344 (11) ratio. In the crystal, there are no identifiable directional interactions between cations and anions except for Coulombic forces.
metal-organic compounds
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In the title compound, [Mg(C3H4O3)2(H2O)2], the Mg2+ cation is six-coordinated by four O atoms from two lactate anions and two aqua ligands, completing an MgO6 distorted octahedral geometry. The complex molecules are bridged by O—HO hydrogen-bonding interactions into helical chains parallel to the a axis, which are linked by further O—HO interactions, forming a three-dimensional supramolecular architecture.
organic compounds
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In the title molecule, C9H3Cl3O3, there are three short interactions involving the benzene H atoms and the chloroformyl Cl atoms. In the crystal, molecules stack along the a axis with no significant non-bonded interactions.
organic compounds
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The title compound, C26H32O11, is composed of an α,β-unsaturated cyclohexanone ring (A), two cyclohexane rings (B and C), a six-membered lactone ring (D) and tetrahydrofuran ring (E). Ring A exists in a half-chair conformation with a C atom displaced by 0.679 (2) Å from the mean plane through the remaining five atoms. Ring B exists in a normal chair conformation. Both rings C and D exist in a twisted-chair conformation due to the O-atom bridge and the carbonyl group in rings C and D, respectively. Ring E shows an envelope conformation with a C atom displaced by 0.761 (1) Å from the mean plane through the remaining five atoms. The ring junctions are A/B trans, B/C trans, C/D cis and D/E cis. An intramolecular O—HO hydrogen bond occurs. In the crystal, O—HO hydrogen bonds involving the hydroxy, lactone and ester groups and C—HO interactions are observed.