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In the title mol­ecule, C10H9NOS2, the 2-sulfanyl­idene­thia­zolidin-4-one mean plane and phenyl ring form a dihedral angle of 81.7 (1)°. In the crystal, C—H...π inter­actions link mol­ecules into helical chains in [010].

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In the cation of the title compound, [Ru(CH3CN)2(C10H8N2)2](BF4)2, the RuII atom is six-coordinated in a distorted octa­hedral geometry by the N atoms of the two 2,2′-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol­ecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86 (12) and 10.12 (14)°. In the crystal, the cations and anions are linked by C—H...F hydrogen bonds into a three-dimensional network.
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