organic compounds
Open access
In the title molecule, C10H9NOS2, the 2-sulfanylidenethiazolidin-4-one mean plane and phenyl ring form a dihedral angle of 81.7 (1)°. In the crystal, C—Hπ interactions link molecules into helical chains in [010].
metal-organic compounds
Open access
In the cation of the title compound, [Ru(CH3CN)2(C10H8N2)2](BF4)2, the RuII atom is six-coordinated in a distorted octahedral geometry by the N atoms of the two 2,2′-bipyridine (bpy) ligands and two cis-arranged acetonitrile molecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86 (12) and 10.12 (14)°. In the crystal, the cations and anions are linked by C—HF hydrogen bonds into a three-dimensional network.