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The structure of 2,3,6,7,10,11-hexa­hydroxy­triphenyl­ene (hhtp) methanol monosolvate, C18H12O6·CH3OH, has triclinic symmetry (space group P\overline{1}). The compound has a three-dimensional layered network structure formed by inter­molecular hydrogen bonding. Structure analysis with Hirshfeld surfaces is shown to be a sensitive method for comparing π-stacking effects in the five known solvates of hhtp. The title structure shows slightly weaker π-stacking than the dihydrate, but stronger π-stacking than the other three solvates.
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