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In the title compound, [RuCl(C18H15P)(C26H31N2OP)](CF3O3S)·2C3H6O, the RuII ion is coordinated in a three-legged piano stool, half-sandwich-type geometry by a chlorido ligand, a tri­phenyl­phosphine and a tethered η6-(phenyl-p-O-meth­oxy) κ1-P N-di­phenyl­phosphino N′-diisopropyl amidine ligand charge-balanced by a trifluormethansulfonate counter-anion. The η6-coordination mode of the arene incorporated into the structure was generated in situ after addition of methyl tri­fluoro­methane­sulfonate to the neutral η5-arene tethered precursor complex [RuCl(PPh3)(η51-OC6H4C(NiPr2)=N-PPh2)] in di­chloro­methane solution.
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