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The title compound, C13H10O5, is a benzophenone derivative containing phloroglucinol and p-hydroxy­benzoyl groups. The p-hydroxy­benzoyl group is twisted out of the plane of the phloroglucinol group as a result of steric hindrance [dihedral angle = 50.2 (1)°]. In the crystal packing, screw-related mol­ecules are linked by O—H...O hydrogen bonds to form a zigzag layer parallel to (10\overline{1}). Adjacent layers are inter­linked by O—H...O hydrogen bonds involving the solvent water mol­ecules.

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The title compound, C17H12O6, forms an infinite one-dimensional zigzag-like chain developing parallel to the b axis through O—H...O hydrogen bonds. The chains are stacked along the c axis. The crystal structure is further stabilized by weak π–π and C—H...π inter­actions.
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