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In the title centrosymmetric compound, C34H30N62+·2PF6, the planes through the pyridine and anthracene ring systems form dihedral angles of 78.8 (1) and 73.5 (1)°, respectively, with the imidazole ring. The crystal packing is stabilized by π–π stacking inter­actions between the anthracene ring system and pyridine rings of adjacent mol­ecules, and also by C—H...N hydrogen bonds.
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