metal-organic compounds
In the title complex, [Co(NH2CH2CH2NH2)2(NO2)2](IO4), the cations are situated on two sets of inversion centres and are linked by pairs of complementary N—HO hydrogen bonds into columns arranged in an approximately hexagonal manner. The periodate anions can be envisaged as occupying triangular hollows above and below approximate hexagonal close-packed layers of trans-bis(ethylenediamine-κ2N,N′)dinitrocobalt(III) cations.