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In the title mononuclear [Ni(phen)3]sq·8H2O complex [phen is 1,10-phenanthroline (C12H8N2) and sq is squarate (C4O42−)], the NiII ion has a distorted octa­hedral coordination geometry composed of six N atoms from three bidentate chelating phen ligands. An extensive three-dimensional network of Owater—H...O, Owater—H...Owater and C—H...O hydrogen-bonding inter­actions is responsible for crystal stabilization.
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