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In the title compound, C10H22N4S2, mol­ecules lie across crystallographic inversion centres. Weak N—H...N and N—H...S hydrogen-bonding inter­actions are observed in the mol­ecular structure.

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The title compound, C16H18N4S2, has a crystallographic inversion centre at the mid-point of the central C—C bond. The plane of the dithio­oxamide fragment is approximately perpendicular to the plane of the dimethyl­ene bridge [dihedral angle = 84.8 (1)°], the plane of which is in turn normal to the pyridine ring plane [dihedral angle = 89.80 (8)°]. An inter­molecular N—H...N hydrogen bond involving the amide NH group and the pyridine N atom [N...N = 3.0503 (18) Å and N—H...N = 145.8 (14)°] links the mol­ecules into chains extending along the c axis.

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The title compound, C28H20N2O2, has a crystallographic inversion centre, and an intra­molecular O—H...N hydrogen bond may have an effect on some bond lengths and angles.

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In the title compound, C14H30N4S2, the mol­ecules lie about crystallographic inversion centres. A weak N—H...S hydrogen-bonding inter­action is observed in the crystal structure.

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Mol­ecules of the title compound, C12H26N4S2, have 2/m symmetry. Intra­molecular N—H...N and N—H...S hydrogen bonds are observed.
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