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In the title compound, C24H27N3O2S·C2H6O, the dihedral angle between the least-squares planes of the 2,5-dihydroxy­benzene ring and the mesit­yl group is 78.59 (6)°. An intra­molecular O—H...N hydrogen bond is observed in the mol­ecular structure. Centrosymmetrically related mol­ecules are linked by N—H...O inter­molecular hydrogen bonds to form a dimer. The dimers are inter­linked by O—H...O and O—H...N inter­molecular hydrogen bonds involving the ethanol mol­ecule of crystallization to form chains along the a axis.

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The structure of the title compound, C38H56N8S2·2C2H6OS, has been determined by single-crystal diffractometry and is compared with the structures of other compounds containing the thio­semicarbazide group. The structure is stabilized by N—H...S hydrogen bonding, resulting in the formation of infinite chains parallel to the [010] axis. The thio­semicarbazone group has an E configuration.

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The title compound, C20H29NOS, the thio­morpholine ring adopts a chair conformation. The crystal structure is stabilized by inter­molecular C—H...π inter­actions.
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