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The title compound, C20H21O7, also known as purpuriol, was isolated for the first time from natural product sources. The cyclo­hexene ring adopts a half-chair conformation with an axially attached methyl benzoate and equatorially attached benzoyl­oxy substituents. The methyl benzoate and benzoyl­oxy groups are essentially planar. The dihedral angle between these groups is 9.2 (2)°. O—H...O intermolecular hydrogen bonds link the mol­ecules into chains along the a axis and the chains are interlinked by C—H...O hydrogen bonds and C—H...π interactions.
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