metal-organic compounds
The title compound, [(OC6H4CH=NCH2COO)SbPh3]·CH2Cl2 or [Sb(C6H5)3(C9H7NO3)]·CH2Cl2, is a mononuclear antimony(V) complex. The asymmetric unit comprises two independent molecules of the complex and two solvent molecules. In both complex molecules, the Sb atoms are in distorted octahedral environments.
organic compounds
In the title compound, C34H30O4, the dihedral angle between the planes of the indene group and the nearer naphthalene ring system is 84.88 (5)°. No significant hydrogen-bonding interactions are observed in the crystal structure.
organic compounds
In the title compound, C15H14ClF3N2O2, the benzene and pyrazolyl rings form a dihedral angle of 15.9 (3)°.
organic compounds
The molecule of the title compound, C11H18ClN5O2, possesses an approximate mirror plane and both morpholine rings adopt chair conformations.
organic compounds
The title compound, C13H14ClN5O, was synthesized from 2,4-dichloro-6-morpholino-1,3,5-triazine and aniline. In the crystal structure, there are intermolecular N—HO hydrogen bonds which propagate infinite chains parallel to the c axis. The morpholine ring adopts a chair conformation.
organic compounds
The title compound, C14H11Br2N, was synthesized by N-alkylation of bromoethane with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar and makes a dihedral angle of 94.7 (3)° with the plane formed by the ethyl C and carbazole N atoms.
organic compounds
Two independent molecules comprise the asymmetric unit of the title compound, C19H13Br2N, which was synthesized by N-alkylation of benzyl bromide with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar and forms a dihedral angle with the pendant phenyl ring of 66.0 (2)° [70.6 (2)° for the second molecule]. In the crystal structure, π–π interactions and weak C—HBr interactions are observed.
organic compounds
In the title compound, C22H15ClN2O2, the molecular structure is stabilized by intramolecular C—HO and C—HN hydrogen bonds. Intermolecular C—HO hydrogen bonds link the molecules into dimers.
organic compounds
The title compound, C18H19Br2N, was synthesized by N-alkylation of 1-bromohexane with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar and the n-hexyl chain is in the fully extended conformation.
organic compounds
In the title compound, C18H14N2, the carbazole and pyridine ring systems are each essentially planar. The asymmetric unit contains three independent molecules. The molecular structure is stabilized by an intermolecular C—HN hydrogen bond.
organic compounds
The title compound, C18H15ClN2O2, contains planar pyrazole, tolyl and chlorophenyl rings. Intermolecular C—HO hydrogen bonds link the molecules into dimers. The carbonyl O atom is found to be disordered.
organic compounds
The molecular structure of the title compound, C16H9BrF4N2O3S, is stabilized by an intramolecular C—HO hydrogen bond. In the crystal structure, supramolecular layers are formed parallel to the bc plane by an intermolecular C—HF hydrogen bond. The CF3 group was found to be disordered.