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The title compound, [(OC6H4CH=NCH2COO)SbPh3]·CH2Cl2 or [Sb(C6H5)3(C9H7NO3)]·CH2Cl2, is a mononuclear antimony(V) complex. The asymmetric unit comprises two independent mol­ecules of the complex and two solvent molecules. In both complex molecules, the Sb atoms are in distorted octahedral environments.

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In the title compound, C34H30O4, the dihedral angle between the planes of the indene group and the nearer naphthalene ring system is 84.88 (5)°. No significant hydrogen-bonding inter­actions are observed in the crystal structure.

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In the title compound, C15H14ClF3N2O2, the benzene and pyrazol­yl rings form a dihedral angle of 15.9 (3)°.

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The mol­ecule of the title compound, C11H18ClN5O2, possesses an approximate mirror plane and both morpholine rings adopt chair conformations.

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The title compound, C13H14ClN5O, was synthesized from 2,4-dichloro-6-morpholino-1,3,5-triazine and aniline. In the crystal structure, there are inter­molecular N—H...O hydrogen bonds which propagate infinite chains parallel to the c axis. The morpholine ring adopts a chair conformation.

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The title compound, C14H11Br2N, was synthesized by N-alkyl­ation of bromo­ethane with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar and makes a dihedral angle of 94.7 (3)° with the plane formed by the eth­yl C and carbazole N atoms.

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Two independent mol­ecules comprise the asymmetric unit of the title compound, C19H13Br2N, which was synthesized by N-alkyl­ation of benzyl bromide with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar and forms a dihedral angle with the pendant phenyl ring of 66.0 (2)° [70.6 (2)° for the second mol­ecule]. In the crystal structure, π–π inter­actions and weak C—H...Br inter­actions are observed.

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In the title compound, C22H15ClN2O2, the mol­ecular structure is stabilized by intra­molecular C—H...O and C—H...N hydrogen bonds. Inter­molecular C—H...O hydrogen bonds link the mol­ecules into dimers.

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The title compound, C18H19Br2N, was synthesized by N-alkyl­ation of 1-bromo­hexane with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar and the n-hexyl chain is in the fully extended conformation.

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In the title compound, C18H14N2, the carbazole and pyridine ring systems are each essentially planar. The asymmetric unit contains three independent mol­ecules. The mol­ecular structure is stabilized by an inter­molecular C—H...N hydrogen bond.

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The title compound, C18H15ClN2O2, contains planar pyrazole, tolyl and chloro­phenyl rings. Inter­molecular C—H...O hydrogen bonds link the mol­ecules into dimers. The carbonyl O atom is found to be disordered.

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The mol­ecular structure of the title compound, C16H9BrF4N2O3S, is stabilized by an intra­molecular C—H...O hydrogen bond. In the crystal structure, supramolecular layers are formed parallel to the bc plane by an inter­molecular C—H...F hydrogen bond. The CF3 group was found to be disordered.
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