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The asymmetric unit of the title compound, C14H16N42+·2C7H4NO4·2C7H5NO4, comprises one-half of the 3,3′-(p-phenyl­enedimethyl­ene)di-1H-imidazol-1-ium dication, which lies on an inversion centre, one 4-nitro­benzoate anion and one 4-nitro­benzoic acid mol­ecule. In the crystal, the components are linked into a two-dimensional network parallel to (110) by O—H...O, N—H...O and C—H...O hydrogen bonds.
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