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The title compound, C21H21N3O3, is a neutral potentially tridentate ligand in an enamine-keto form, stabilized by an intra­molecular N—H...O hydrogen bond. There are two mol­ecules in the asymmetric unit.

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The title compound, C5H5NOS, was synthesized by oxidation of 5-(β-hydroxy­ethyl)-4-methyl­thia­zole, resulting in the breaking of a C—C bond. The non-H atoms of the mol­ecule are almost coplanar. In the crystal structure, no short contacts are observed between symmetry-related mol­ecules.
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