[1,2-Bis­(di­phenyl­phosphino)­ethane]­di­chloro­(methoxo)­oxorhenium(V) di­chloro­methane solvate

The title compound, [Re(CH₃O)Cl₂O(C₂₆H₂₄P₂)]·CH₂Cl₂, contains slightly distorted octahedrally coordinated mol­ecules in which the methoxo group is trans to the oxo ligand. A cis arrangement of the Cl atoms is imposed in the equatorial plane by the bidentate diphosphine ligand. The methoxo group is approximately end-on coordinated [Re-O-CH₃ = 168.1 (5)°].

Chloro­[η⁵-1-(dimethyl­amino­eth­yl)inden­yl](triphenyl­phosphine)nickel(II) dieth­yl ether hemisolvate

The title complex, [Ni(C₁₃H₁₆N)Cl(C₁₈H₁₅P)]·0.5C₄H₁₀O, consists of an Ni^II center coordinated by a dimethyl­amino­eth­yl-substituted inden­yl ligand, a triphenylphosphine ligand and a chloride ion. The asymmetric unit includes two very similar mol­ecules that show only small conformational differences in the inden­yl side chain.

catena-Poly[[silver(I)-μ₂-1,1′-dimethyl-2,2′-biimidazole-κN³:N^3′] nitrate 1.167-hydrate methanol 0.33-solvate]

The title structure, {[Ag(C₈H₁₀N₄)]NO₃·1.167H₂O·0.33CH₄O}_n, consists of helical chains in which approximately linearly coordinated Ag atoms alternate with bridging 1,1′-dimethyl-2,2′-biimidazole ligands in a syn conformation. The environment of each Ag atom is completed by weak Ag—O bonds to a bidentate nitrate ion.

{2,6-Bis[(dimethyl­amino)meth­yl]phenyl-κ²N,C¹,N′}chloro­nickel(II)

The title complex, [Ni(C₁₂H₁₉N₂)Cl], consists of a slightly distorted square-planar Ni^II center coordinated by an anionic terdentate NCN pincer-type ligand, where both N atoms are trans to each other, and by a chloride ion. It is isostructural with two platinum analogues.