metal-organic compounds
The title compound, [Re(CH3O)Cl2O(C26H24P2)]·CH2Cl2, contains slightly distorted octahedrally coordinated molecules in which the methoxo group is trans to the oxo ligand. A cis arrangement of the Cl atoms is imposed in the equatorial plane by the bidentate diphosphine ligand. The methoxo group is approximately end-on coordinated [Re-O-CH3 = 168.1 (5)°].