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In the title compound, [Re(CF3COO)(C20H24N2)(CO)3], the Re atom has a distorted octahedral configuration. The 1,4-di­aza­buta­diene part of the donor ligand and two carbonyl groups occupy the equatorial plane of the complex, with the third carbonyl ligand and the tri­fluoro­acetate group in the axial positions. The equatorial di­imine ligand is bound to the Re center in an N,N'-bidentate chelating fashion, leading to a five-membered ReN2C2 chelate ring with an N-Re-N bite angle of 73.4 (2)°.
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