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Titanium oxyflouride, TiOF2, synthesized via a metathetic displacement reaction, was found to possess a hexagonal (R
c) crystal structure at room temperature, unlike previous reports for this material. Upon heating through 333-338 K, the hexagonal TiOF2 transformed into a cubic (Pmm) polymorph.
c) crystal structure at room temperature, unlike previous reports for this material. Upon heating through 333-338 K, the hexagonal TiOF2 transformed into a cubic (Pmm) polymorph.
