organic compounds
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The asymmetric unit of the title compound, C20H24N2O4·H2O, contains one half-organic molecule (an inversion centre generates the other half of the molecule) and a half-molecule of water (the O atom has site symmetry 2). The near planarity of the fused-benzene ring is illustrated by the very small deviations of all the atoms from the plane [largest deviation = 0.0092 (11) Å. The six-membered N,O-containing ring adopts a half-chair conformation. The observed N—CH2 and CH2—O bond lengths can be correlated to the manifestation of an anomeric effect in the N—CH2—O unit. In the crystal, the molecules are connected into zigzag chains parallel to [001] through O—HN hydrogen bonds formed between the oxazinic N atom and the solvent water molecule. The chains are consolidated by C—HO interactions.