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The title compound, Li+·C24BF20·2C6H6, crystallizes as centrosymmetric dimers, with two η6-coordinated and two uncoordinated mol­ecules of benzene per dimer. There are two crystallographically independent dimers.

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The title compound, C14H12ClNO, is used in perfumery, as a catalyst for the polymerization of olefins, and in organic synthesis, especially as a photosensitizer and in the manufacture of dyes. The mol­ecule is essentially planar and has a trans configuration. In this configuration, the Cl and O atoms shield the amino H atom, preventing the formation of an inter­molecular hydrogen bond.
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