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The crystal structure of the title compound, [Cu(C6H6N4)2(H2O)](NO3)2, has been determined from single-crystal X-ray diffraction data. The five-coordinate geometry of the copper(II) centre comprises four N atoms from two bi­imidazole ligands and a water mol­ecule in a distorted square-based pyramidal coordination. Cu and the aqua ligand lie on a twofold rotation axis.
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