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In the title compound, [Mn(C12H8N6)3](ClO4)2·2CHCl3, the MnII ion is chelated by three 1,10-phenanthroline molecules in a twisted octahedral coordination geometry. In the crystal structure, there are intermolecular π–π interactions between adjacent phenanthroline rings.

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In the title mol­ecule, C23H25NO, the hydroxy H atom is involved in the formation of an intramolecular O—H...N hydrogen bond. The dihedral angle between the benzene ring and the 2-naphthol system is 78.1 (1)°. The crystal packing is stabilized by van der Waals forces.
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