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In the title compound, (C9H8N)2[ZnCl4]·2H2O, the tetra­chlorido­zincate ion is located on a twofold rotation axis with the Zn atom on a special position. The crystal packing is stabilized by N—H...O and O—H...Cl inter­actions.

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In the title compound, the CuII atom has a distorted octa­hedral coordination sphere coordinated by the N atoms of two propane-1,3-di­amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):369 (9)].
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