{2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ²N,N′}(η³-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate

The title compound, [Pd(C₃H₅)(C₁₇H₁₅N₃S₂)]PF₆, is built up by a [(η³-all­yl)Pd]²⁺ fragment coordinated by a 2,6-bis­[(pyridin-2-yl)sulfanylmeth­yl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The Pd^II atom is tetra­coordinated in a strongly distorted square-planar environment mainly determined by the η³-allyl anion in which the central C atom is disordered over two equally occupied positions. The crystal packing is very compact and is characterized by a three-dimensional network of C—H...F interactions between the F atoms of each anion and several H atoms of the surrounding cationic complexes.

Poly[(μ₄-decanedio­ato)cobalt(II)]

In the title compound, [Co(C₁₀H₁₆O₄)]_n, the Co^II atom is bonded in a slightly distorted tetra­hedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network coordination polymer, there are two different spatial extensions of Co^II atoms, one with the Co^II atoms lying parallel to (100) [Co...Co = 4.653 (1) Å], the other lying parallel to (010) [Co...Co = 4.764 (1) Å].