organic compounds
Open access
In the cation of the title compound, C14H13BrN+·C7H7O3S−, the dihedral angle between the benzene and pyridine rings is 8.34 (11)°. The Br atom is disordered over two positions with site occupancies of 0.74 (2) and 0.26 (2). The molecular structure is stabilized by a weak intramolecular C—HO interactions. The crystal structure exhibits weak C—HO and π–π [centroid–centroid distance = 3.7466 (17) Å] interactions, forming a three dimensional network.
organic compounds
Open access
In the title salt, C8H12N+·C7H5O3−, the cation is disordered over two orientations with site occupancies of 0.565 (7) and 0.435 (7). In the anion, the carboxylate group makes the dihedral angle of 4.19 (18)° with the benzene ring. In the crystal, the ions are connected by N—HO and O—HO hydrogen bonds, forming a three-dimensional network.