metal-organic compounds
Open access
In the title compound, [CoCl(C2H7N)(C3H10N2)2]Cl2, the CoIII ion has a distorted octahedral coordination environment and is surrounded by four N atoms in the equatorial plane, with the other N and Cl atoms occupying the axial positions. The crystal packing is stabilized by N—HCl hydrogen bonds, forming a layered arrangement parallel to (1-10).
metal-organic compounds
Open access
In the title compound, [CoCl(CH5N)(C3H10N2)2]Cl2·H2O, the CoIII ion has an octahedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions. The crystal packing is stabilized by intermolecular N—HO, N—HCl, and O—HCl interactions, generating a three-dimensional network.