organic compounds
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The asymmetric unit of the title compound, C13H11NO6, contains two molecules in both of which the six-membered 1,3-dioxane-4,6-dione ring shows a screw-boat conformation. The dihedral angles between the best planes through the six-membered rings are 47.8 (2) and 49.8 (2)°. In the crystal, C—HO interactions link the molecules, building a supramolecular sheet parallel to the c axis.
organic compounds
Open access
The title bis-piperidine, C26H28N2O3, was unexpectedly obtained via a dimerization mechanism promoted by acetic acid when performing the Dieckmann cyclization of a chiral amido ester. The S,S configuration was assigned by reference to the enantiomerically pure starting material. In the molecule, two core heterocycles are linked by a σ bond. One ring includes a keto–enol group, while the other presents an enone functionality. Both rings present a conformation intermediate between envelope and screw-boat, and the dihedral angle between the mean planes passing through the rings [48.9 (1)°] is large enough to avoid hindrance between ring substituents. The enol tautomeric form in one ring favors the formation of strong intermolecular O—HO=C hydrogen bonds. The resulting one-dimensional supramolecular structure features single-stranded helices running along the 21 screw axis parallel to [100].
organic compounds
Open access
The unit-cell dimensions and space group of the second monoclinic polymorph of the title compound, C15H11FO, differ from those of the previously reported form [Jing (2009). Acta Cryst. E65, o2515]. The title compound shows an E conformation of the C=C bond with the 4-fluorophenyl group opposite to the benzoyl group. The torsion angle of between the planes of the 4-fluorophenyl and benzoyl groups is 10.53 (6)°. In the crystal, weak C—HO and C—HF interactions form a cross-linked packing motif, building sheets parallel to (-102).