metal-organic compounds
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In the title compound, [Pb(C14H14O2PS2)2]n, the metal atom is surrounded by two O,O′-bis(2-methylphenyl) dithiophosphate ligands bonding through the S-donor atoms. Three of the Pb—S bond lengths are are close to each other at 2.7710 (18), 2.8104 (16) and 2.8205 (16) Å, while the fourth Pb—S bond is elongated at 3.0910 (18) Å and reflects the fact that this atom is involved in intermolecular bridging to an adjacent PbII atom [Pb—S = 3.145 (2) Å]. The bond angles demonstrate that the PbII atom contains a stereochemically active lone pair with a distorted octahedral geometry about the PbII atom. This distortion is shown by the S—Pb—S bite angles of 73.63 (4) and 69.50 (4)°, while the remaining S—Pb—S angles range from 81.03 (5) to 143.66 (5)°. One of the benzene rings shows positional disorder over two orientations with occupancy factors of 0.747 (11) and 0.253 (11).