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In the title compound, C6H3ClN2SSe, the selenadiazole and chloro­thio­phene rings are almost coplanar [dihedral angle = 5.24 (15)°]. In the crystal, C—H...N inter­actions link the mol­ecules into chains extending along the b-axis direction. C—H...π inter­actions also occur.

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In the title compound, [CoCl(C2H7N)(C3H10N2)2]Cl2, the CoIII ion has a distorted octa­hedral coordination environment and is surrounded by four N atoms in the equatorial plane, with the other N and Cl atoms occupying the axial positions. The crystal packing is stabilized by N—H...Cl hydrogen bonds, forming a layered arrangement parallel to (1-10).
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