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The title compound, [Cu(C3H6NO3)2(H2O)2]·0.1H2O, is isostructural with the nickel analogue. The octa­hedral CuII ion lies on a twofold axis, with cis chelating O,N-serine groups and trans aqua ligands. Small amounts of a solvent water molecule form hydrogen bonds to link the mol­ecules along the [010] direction, while a number of strong hydrogen bonds combine to form sheets in the (110) plane.
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