organic compounds
In the crystal structure of the title compound, (4aR,5R,6S,7S,8aS)-methyl 8a-ethenyloctahydro-5-acetoxy-7-{[2-(acetoxymethyl)-1-oxo-2-propenyl]oxy}-α,4-bis(methylene)-3-oxo-1H-2-benzopyran-6-acetate, C24H28O10, the molecule has a cis configuration at the junction of the two six-membered rings and not a trans configuration as was assigned on the basis of NMR data in solution [Asaka et al. (1977). Phytochemistry, 16, 1838–1839].