metal-organic compounds
Open access
In the title complex, (C16H36N)[WCuO2S2(C3H6N2S)], the W and Cu atoms have tetrahedral and trigonal-planar coordination, respectively. Two sulfide ligands bridge the two metal centres; tungsten is additionally coordinated by two terminal oxo ligands and copper by the exocyclic S atom of imidazolidine-2-thione. There is an intramolecular N—HS hydrogen bond in the anion, and anions are linked into chains by N—HO intermolecular hydrogen bonds. The more loosely held cation is disordered.
organic compounds
Open access
The structure of the monohydrate of α-4-(β-D-galactopyranosido)-D-glucopyranose, more commonly known as α-lactose monohydrate, C12H22O11·H2O, has been previously studied by single-crystal diffraction at ca 296 K [Beevers & Hansen (1971). Acta Cryst. B27, 1323–1325; Fries et al. (1971). Acta Cryst. B27, 994–1005; Noordik et al. (1984). Z. Kristallogr. 168, 59–65]. This redetermination at low temperature [150 (2) K] shows improved precision of geometry. Graph-set analysis of the hydrogen-bonding motifs is presented for the first time.