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In the title compound, C25H20O3, two of the benzene rings are almost perpendicular to each other, with a dihedral angle of 88.1 (1)°. The mol­ecular packing is stabilized by inter­molecular C—H...O and π–π inter­actions, in addition to van der Waals forces.

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The title compound, C28H22ClNO3, has two crystallographically independent mol­ecules in the asymmetric unit. The pyrrolidine ring (A) of the pyrrolizine system adopts an envelope conformation in both mol­ecules, whereas the other five-membered ring (B) adopts an envelope conformation in one mol­ecule and a twist conformation in the other. The mol­ecular packing is stabilized by inter­molecular C—H...O, C—H...π and π–π inter­actions.

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In the title compound, C19H21BrN2O2S, the fused pyrrolidine rings adopt envelope conformations. The mol­ecular packing is stabilized by weak inter­molecular C—H...O inter­actions and van der Waals forces.

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In the title cyclo­adduct, C20H19N3O3, the mol­ecules form centrosymmetric dimers linked by N—H...O hydrogen bonds, forming an R22(8) ring. The overall conformation of the pyrrolizidine nucleus is folded about the bridging bond.

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In the title compound, C19H19N3O3, the oxindole residue and the 4-methyl­phenyl ring are almost perpendicular to the pyrrolidine ring. The pyrrolidine ring adopts an envelope conformation. The mol­ecular packing is stabilized by N—H...O hydrogen bonds and C—H...O inter­actions, in addition to van der Waals forces.
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