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The enantiomerically pure title compound, C18H20O2, crystallizes with one mol­ecule in the asymmetric unit. The packing arrangement is significantly different from that of its racemate. Linear hydrogen-bonded chains are aligned along the [100] direction. Edge-to-face π–π interactions occur between adjacent hydrogen-bonded columns.

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The title compound, C21H26NO2S, was obtained during the synthesis of the thiol derivative of Dianin's compound. Unlike Dianin's compound and the thiol derivatives, the title compound revealed no strong hydrogen-bonding inter­actions.

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The mol­ecules of 1,1-dibenzoyl-3,3-dimethyl­urea, C17H16N2O3, inter­act through an inter­molecular C—H...O hydrogen bond and several C—H...π inter­actions, resulting in a three-dimensional network.
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