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The title compound, C7H7I2NO2+·I·C7H6I2NO2, crystallizes with Z′ = 1 \over 2; the iodide anion lies on a twofold axis, and in the cation/zwitterion adduct the acidic H atom is disordered over an inversion centre. The residues are linked to form zigzag chains in the overall direction [103] by I...I interactions between anion and cation, and by classical O—H...O hydrogen bonds. Weak hydrogen bonds C—H...O link the chains to form layers parallel to (30\overline 1).
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