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In the crystal structure of the title compound, [Co2(SO4)2(C5H5N)6(H2O)2]·4H2O, the sulfate dianion bridges a (C5H5N)4Co unit to a (C5H5N)2(H2O)2Co unit, forming a chain that runs along the a axis of the monoclinic unit cell. The Co atoms of the units lie on special positions, each of \overline{1} site symmetry. Adjacent chains are linked through the uncoordinated water mol­ecules into layers.

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The mol­ecules of the title compound, C16H16N2O4, are linked by hydrogen bonds into a zigzag chain running along the c axis of the monoclinic cell.

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The mol­ecules of the title compound, C14H12N2O3, are linked via hydrogen bonds into a chain running along the shortest axis of the orthorhombic cell.

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The mol­ecule of the title compound, C12H10N2O4, is planar and two mol­ecules are stacked over one another at a distance of 3.6 Å. The mol­ecules are linked by hydrogen bonds into a three-dimensional network.

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The two independent mol­ecules of the title compound, C12H10N2O3S, are approximately planar and one is stacked over the other. One of the two mol­ecules inter­acts with its symmetry-related neighbors to form a hydrogen-bonded helical chain that runs along the shortest axis of the orthorhombic unit cell. The second independent mol­ecule does not form such a chain; instead, it is merely linked to the other independent mol­ecule by a hydrogen bond.

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Mol­ecules of 5-chloro­salicylaldehyde benzoyl­hydrazone, C14H11ClN2O2, are linked by an inter­molecular amino-carbon­yl hydrogen bond into a linear chain that runs along the a axis of the orthorhombic unit cell.

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Nearly planar mol­ecules of the title compound, C11H11N3O4, are linked by O—H...O hydrogen bonds to form zigzag chains along the c axis; adjacent chains are, in turn, linked by weaker N—H...O hydrogen bonds to form layers perpen­dic­ular to the a axis of the ortho­rhom­bic unit cell.
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