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In the title mol­ecule, C14H13IN2O3S, the dihedral angle between the planes of the benzene and toluene rings is 84.3 (3)°. The mol­ecule displays a trans conformation with respect to the C=N bond. There is an intra­molecular O—H...N hydrogen bond with the azomethine N atom as acceptor. In the crystal, N—H...O hydrogen bonds connect the mol­ecules into chains running along the b axis.

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In the title compound, 2C12H24N+·C6H6O72−·C2H6O, the cyclo­hexane rings of the cations adopt chair conformations. In the anion, intra­molecular O—H...O hydrogen bonds occur. In the crystal, the cations link with the anions via N—H...O hydrogen bonds. Weak C—H...O hydrogen bonds are also observed. The hy­droxy group of the ethanol solvent mol­ecule is disordered over two sets of sites with an occupancy ratio of 0.766 (5):0.234 (5).
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