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The non-H atoms of the title compound, C10H8N4OS, lie approximately in a common plane (r.m.s. deviation = 0.058 Å). In the crystal, two mol­ecules are linked across a center of inversion by a pair of N—H...N hydrogen bonds, forming a a dimer.

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The triazoloquinazoline fused-ring system of the title compound, C10H8N4O3S, is essentially planar (r.m.s. deviation = 0.027 Å). In the crystal, adjacent mol­ecules are linked by N—H...Osulfon­yl hydrogen bonds, generating a helical chain running along the b axis.
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