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The complete molecule of the compound, C6H4N8O3, is generated by a crystallographic twofold rotation axis that runs through the central ring. The flanking ring is twisted by 20.2 (1)° with respect to the central ring. One of the amino H atoms forms an intra­molecular N—H...N hydrogen bond; adjacent mol­ecules are linked by N—H...N hydrogen bonds forming a chain running along [10-2].
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