metal-organic compounds
Open access
In the title compound, [Mn(C12H8NO2)2(H2O)4], the Mn2+ ion lies on a twofold rotation axis and has a distorted N2O4 octahedral coordination geometry formed by four water O atoms in the equatorial plane and two apical pyridyl N atoms. A three-dimensional network is formed in the crystal structure by multiple O—HO hydrogen bonds between the coordinating water molecules and the free carboxylate groups.
metal-organic compounds
Open access
catena-Poly[[diaquanickel(II)]-bis(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)]
In the title compound, [Ni(C9H6N3O3S)2(H2O)2]n, the NiII atom, located on an inversion center, is ligated in an octahedral geometry by two carboxylate O atoms from two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate (L) ligands and two O atoms from water molecules in the equatorial plane, and two pyridine N atoms from other two L ligands at the apical sites. Two L ligands bridge pairs of metal atoms in an antiparallel manner, forming centrosymmetric dinuclear quasi-rectangular units which are linked into infinite double-stranded chains parallel to [100]. O—HO hydrogen bonds between the coordinating water molecules and the carboxylate groups of the L ligand as well as interchain SN interactions [2.726 (2)–3.363 (2) Å] lead to the formation of a layer structure parallel to (001).