metal-organic compounds
Open access
The Pd atom in the title compound, [Pd(C18H14O3P)Cl(C5H8N2)], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—HO and C—HCl hydrogen-bond interactions. One of the phenyl rings is disordered over two almost equally occupied sites.
metal-organic compounds
Open access
In the title compound, [PdCl2(C21H21O3P)2], the Pd atom adopts a slightly distorted square-planar coordination geometry, with pairs of the equivalent ligands in cis positions. Adjacent molecules are linked by weak C—HCl hydrogen bonds. The crystal structure is additionally stabilized by π–π stacking interactions between the aromatic rings [shortest centroid–centroid distance = 3.758 (4) Å].