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The reaction of (η3-all­yl)[(1,2,5,6-η)-cyclo­octa-1,5-diene]rhodium(I) with tris­(2,4-di-tert-butyl­phen­yl)phosphite in toluene produces the title compound, [Rh(C42H62O3P)(C8H12)]·C7H8, by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite mol­ecule. The coordination geometry at the RhI ion is distorted square-planar. The toluene solvent mol­ecule is disordered over two different orientations, with site-occupation factors of 0.810 (2) and 0.190 (2).

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In the title compound, [Rh(C74H68O8P2)H(CO)2]·C4H10O, the C2HP2 coordination set at the RhI ion is arranged in a distorted trigonal–planar geometry with one P atom of the diphosphite mol­ecule and the H atom adopting the axial coordination sites.
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