organic compounds
Open access
In the title compound, C21H25NO3·C2H4O2, the piperidone ring adopts a chair conformation. The two methoxy groups are nearly coplanar with the aromatic rings to which they are attached. The dihedral angle between the two aromatic rings is 60.9 (2)°. There are two short intramolecular N—HO contacts. The crystal packing is stabilized by intermolecular O—HN and C—HO interactions.
organic compounds
Open access
In the title compound, C20H20BrNO2, the piperidone ring adopts a boat conformation. The phenyl rings are oriented at dihedral angles of 97.8 (2) and 96.0 (1)° with respect to the best plane through the piperidine ring. The dihedral angle between the two phenyl rings is 49.7 (1)°. In the crystal, bifurcated C—HO hydrogen bonds form a R21(7) ring motif, linking the molecules into centrosymmetric dimers.