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In the structure of the title compound, [KPt(C6H4N3O)Cl2(C6H5N3O)(C12H24O6)], the PtII atom is in a distorted square-planar geometry. The crystal structure is consolidated by O—H...O hydrogen bonds. The measured crystal was a non-merohedral twin with four components.

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In the title compound, [K2PtCl4(C12H24O6)2], the PtII ion is located on an inversion centre and is coordinated by four Cl atoms, forming a square-planar geometry. The KI ion is coordinated by six O atoms of the crown ether and two bridging Cl atoms. The KI ion is displaced by 0.756 (2) Å from the mean plane of the six O atoms of the crown ether. The mol­ecules are connected by weak C—H...O hydrogen bonds, forming an infinite two-dimensional network parallel to the (10\overline{2}) plane. Intra- and inter­molecular C—H...Cl hydrogen bonds are also observed.
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